Postage internationally - exclude locations

Even though I've updated my preferences so many times I'm blue in the face, I am still getting buyers from Canada, when my preferences say I do not post to Canada.

 

I have updated site preferences - shipping preferences  - and ticked "also apply to current listings" but it just doesn't seem to "take".    Any suggestions, please.  

 

The listing itself says no postage to Canada - but they still can buy - I don't understand it.