How can I ask for more postage on international postage please?

I only post to Australia and last week I sold an item to a buyer who ebay said was in the UK.   I sent an email stating I only sold to Australia and also stating that postage would be very high and was he still interested.  No reply.   I sent an invoice with postage set at $64 on a $15 item!    He paid today but Paypal says to post to the United Arab Emirates which, with a confirmation fee of $3.85, means I will need another $6.40 from the buyer for the extra postage.

 

Do I just email him or can I send another invoice?    If so, how?   Thanks for your help.

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